Selective S-arylation of thiols with o-OTf-substituted diaryliodonium salts toward diarylsulfides

文献情報

出版日 2023-12-13

DOI 10.1039/D3OB01922E

インパクトファクター 3.876

著者

Yuxuan Zhang, Yu Wang, Limin Wang, Jianwei Han

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要旨

In contrast to the previously reported intramolecular aryl migration, we present the selective sulfenylation of ortho-trifluoromethanesulfonate (OTf) substituted diaryliodonium salts with thiols. As such, diarylsulfides bearing vicinal OTf groups were synthesized in good yields. The unique reactivity of the vicinal OTf group and the sulfur atom in arylsulfides offers further transformations.

掲載誌

Organic & Biomolecular Chemistry

CiteScore: 3.4

自己引用率: 10.3%

年間論文数: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Selective S-arylation of thiols with o-OTf-substituted diaryliodonium salts toward diarylsulfides

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