Towards improved comprehensive energetic properties by skeleton modification

文献情報

出版日 2023-12-11

DOI 10.1039/D3NJ05248F

インパクトファクター 3.591

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要旨

Skeleton modification is an effective way of tuning and achieving desired properties for energetic compounds. In this work, a series of energetic compounds based on the [1,2,4]triazolo[3,4-f][1,2,4]triazine-8(7H)-one backbone have been designed and synthesized. After the skeleton modification of compound 5, the resulting compound 6, which has the same type of energetic group, exhibits higher density (1.951 g cm−3), and better thermal stability and mechanical sensitivities than those of compound 5. Moreover, its energetic hydrazinium salt 8 has a high detonation property (D = 9003 m s−1; P = 30.9 GPa). This research may provide new insights into the design and synthesis of novel energetic compounds with balanced comprehensive properties.

掲載誌

New Journal of Chemistry

CiteScore: 5.3

自己引用率: 3.7%

年間論文数: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Towards improved comprehensive energetic properties by skeleton modification

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