Adsorptive separation of saccharides and polyols over materials functionalized with boronate groups
文献情報
Irina Delidovich, Valérie Toussaint
Saccharides and polyols play key roles in emerging biomass-based value chains, though recovery of these compounds from product streams remains challenging. This Review addresses the application of materials bearing boronate groups for separation and recovery of saccharides and polyols via affinity adsorption processes. First, the representative, industrially important product mixtures are considered, along with the design of separation processes exploiting the affinity adsorption. Thereafter, the structure-performance correlations are critically discussed for gel-type functionalized polymers, macroporous resins, molecularly imprinted polymers, and materials bearing grafted phenylboronate moieties and grafted polymer brushes. Finally, the separation processes based on functional materials bearing boronate groups are compared with the state-of-the-art chromatographic separation over Ca2+ ion-exchange resins. This analysis aims at identifying guidelines for rational material synthesis and knowledge-driven process design for novel economically viable and environmentally benign separation processes.
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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.



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