Role of electron and hole doping in the NdNi1−xVxO3 nanostructure
文献情報
Raktima Basu, Reshma Kumawat, Mrinmay Sahu, Abu Bakkar Miah, Partha Mitra, Goutam Dev Mukherjee
Neodymium nickelate, NdNiO3, attracts attention due to the simultaneous occurrence of several phase transitions around the same temperature. The electronic properties of NdNiO3 are extremely complex as structural distortion, electron correlation, charge ordering, and orbital overlapping play significant roles in the transitions. We report the effects of electron and hole injection via doping a single 3d metal, V, in the NdNiO3 nanostructure to understand the variations in the electronic properties without any structural distortion. A reversible resistivity modulation of more than five orders of magnitude via hole doping and complete suppression of the metal to insulator transition via electron doping is observed along with the switching of major charge carriers. The modulation of electronic properties without any structural distortion and external strain opens up new directions to consider the NdNi1−xVxO3 nanostructures applicable as emerging electronic devices.
関連文献
Calculating binding free energies of host–guest systems using the AMOEBA polarizable force field
David R. Bell, Rui Qi, Zhifeng Jing, Jin Yu Xiang, Christopher Mejias, Michael J. Schnieders, Jay W. Ponder, Pengyu Ren
DOI: 10.1039/C6CP02509A
Modulation of the exfoliated graphene work function through cycloaddition of nitrile imines‡
Myriam Barrejón, María J. Gómez-Escalonilla, José Luis G. Fierro, Pilar Prieto, José R. Carrillo, Gonzalo Abellán, M, Mercedes Gabás, Juan T. López-Navarrete, Fernando Langa
DOI: 10.1039/C6CP05285A
Efficient charge transfer and utilization of near-infrared solar spectrum by ytterbium and thulium codoped gadolinium molybdate (Gd2(MoO4)3:Yb/Tm) nanophosphor in hybrid solar cells
Weifu Sun, Zihan Chen, Qin Zhang, Junli Zhou, Feng Li, Xiao Jin, Dongyu Li, Qinghua Li
DOI: 10.1039/C6CP04963J
A DFT kinetic study on 1,3-dipolar cycloaddition reactions in solution
Shi-Jun Li, De-Cai Fang
DOI: 10.1039/C6CP05190A
Water inhibits CO oxidation on gold cations in the gas phase. Structures and binding energies of the sequential addition of CO, H2O, O2, and N2 onto Au+
J. Ulises Reveles, Khaled M. Saoud, M. Samy El-Shall
DOI: 10.1039/C6CP05431E
Solvent effects on ion–receptor interactions in the presence of an external electric field
Martin Novák, Cina Foroutan-Nejad
DOI: 10.1039/C6CP05781K
Geometric and electronic properties of gold clusters doped with a single oxygen atom
Xun-Lei Ding, Heng-Lu Liao, Yi-Ming Chen, Dan Wang, Ya-Ya Wang
DOI: 10.1039/C6CP05595H
Elucidation of the conformational dynamics of multi-body systems by construction of Markov state models
Fu Kit Sheong
DOI: 10.1039/C6CP02545E
こちらもおすすめ
6- bromo-1-cyclopropyl-1H-benzimidazoleの市場動向や研究トレンドはどうですか?
6- bromo-1-cyclopropyl-1H-benzimidazoleは、抗炎症、抗ウイルス作用を持つことが報告されており、新薬開発の研究対象として注目...
環氧プロpanol-d5を取り扱う際の実験室安全事項は何ですか?
取り扱う際には、防護眼鏡と手袋を使用し、ドラフトチャンバー内で操作することを推奨します。漏洩時には適切な手順で処理し、安全データシートを常に参照してください。
2,2’-ジメチル-3,3’-ビピリジンはどのように合成されますか?
2,2’-ジメチル-3,3’-ビピリジンは、ピリジンと2-メチルアクリルアミドを有機合成反応で合成します。この反応では、ピリジンと2-メチルアクリルアミドを含有...
6-甲基ピリジン-2-ボリック酸の主な用途は何ですか?
6-甲基ピリジン-2-ボリック酸は、合成化学、医薬品合成、以及研究用途などに広く使用され、特に組換えDNA技術や分子生物学の研究において重要な役割を果たします。
(R)-3-(1-甲基-2-氧環己基)プロpano酸メチルは安全ですか?
(R)-3-(1-甲基-2-氧環己基)プロpano酸メチルは一定の安全性がありますが、直接的な皮膚接触や吸入は避けるべきです。使用する際は適切な個々の安全データ...
ketorolacはどのように保存すればよいですか?
ketorolacは、密封して遮光容器に保管し、直射日光や高温を避けて保存してください。温度は常温で保存し、湿度をなるべく低く保つことが推奨されます。
L-2,3-二氨基丙酸二盐酸盐を取り扱う際の実験室安全事項は何ですか?
L-2,3-二氨基丙酸二盐酸盐は腐食性が強く、皮膚や粘膜に刺激を与える可能性があります。取り扱う際は、防塵マスク、ゴーグル、手袋を使用し、適切な排気設備を使用し...
2-(4-溴ピリジン-2-基)乙腈の物理化学的性質は何ですか?
2-(4-溴ピリジン-2-基)乙腈のCAS番号は312325-73-8です。主に結晶形態で存在し、分子量は159.01 g/molです。この化合物は水に溶けやす...
3-フローロ-[1,1-ベンジレン]-3,4-ジカルボン酸を取り扱う際の実験室安全事項は何ですか?
この化合物は毒性は低いですが、直接的な接触や吸入に注意が必要です。PPE(個人防護具)を着用し、ドラフトチャンバーを使用して操作することを推奨します。また、漏洩...
3-(1-氧代-1,3-二氢-2H-2-异吲哚)丙酸の主な用途は何ですか?
3-(1-氧代-1,3-二氢-2H-2-异吲哚)丙酸は、薬理学研究や医薬品製造において広く用いられる化合物です。また、工業的な用途でも一部の化学反応の触媒や助剤...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














