Steric control of Mg–Mg bond formation vs. N2 activation in the reduction of bulky magnesium diamide complexes

文献情報

出版日 2023-12-19

DOI 10.1039/D3CC05787A

インパクトファクター 6.222

著者

Rahul Mondal, Matthew J. Evans, Dat T. Nguyen, Thayalan Rajeshkumar, Laurent Maron, Cameron Jones

原文を見る

要旨

Reduction of the magnesium(II) diamide [Mg(TripNON)] (TripNON = 4,5-bis(2,4,6-triisopropylanilido)-2,7-diethyl-9,9-dimethyl-xanthene) with 5% w/w K/KI leads to a good yield of a dianionic dimagnesium(I) species, as its potassium salt, [{K(TripNON)Mg}2]. An X-ray crystallographic analysis shows the molecule to contain a very long Mg–Mg bond (3.137(2) Å). The formation of [{K(TripNON)Mg}2] contrasts with a previously reported reduction of a magnesium(II) complex incorporating a bulkier diamide ligand, which instead afforded a magnesium–dinitrogen complex. In the current study, [{K(TripNON)Mg}2] has been shown to be a viable reagent for the reductive activation of CO, H2 and N2O.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Steric control of Mg–Mg bond formation vs. N2 activation in the reduction of bulky magnesium diamide complexes

文献情報

おすすめジャーナル

関連文献

Photon management properties of rare-earth (Nd,Yb,Sm)-doped CeO2 films prepared by pulsed laser deposition

White light emission from a two-component hybrid gel via an energy transfer process

Role of RuO2(100) in surface oxidation and CO oxidation catalysis on Ru(0001)

Mechanisms of low temperature capture and regeneration of CO2 using diamino protic ionic liquids

Suspensions of carbon nanofibers in organic medium: rheo-electrical properties

Photobleaching and stabilization of carbon nanodots produced by solvothermal synthesis

Deep traps can reduce memory effects of shallower ones in scintillators

Playing with isomerism and N substitution in pentalenedione derivatives for organic electrode batteries: how high are the stakes?

Structural variety beyond appearance: high-pressure phases of CrB4 in comparison with FeB4

Origins of ultralow thermal conductivity in bulk [6,6]-phenyl-C61-butyric acid methyl ester (PCBM)

こちらもおすすめ

カルボニル基が付いた5-氰基-1-{[(2-メチル-2-プロpanyl)オキシ]カーボンイル}1H-吲哚-2-イリド-2-ボリン酸はどのように保存すればよいですか？

tert-ブチル2-クロロメチルピリジン-3-基炭酸エステルの市場動向や研究トレンドはどうですか？

聚二季戊四醇六丙烯酸酯はどの業界で使用されていますか？

1-氯-5-硝基异喹啉の市場動向や研究トレンドはどうですか？

2-チロール-5-メチルスルフェニル-3-trifルオルメチルベンゼンはどのように合成されますか？

p-トールイルマグネシウムブロミドの物理化学的性質は何ですか？

1-(5-甲基-2-硫化素基)プロパン-1-酮の市場動向や研究トレンドはどうですか？

十一碳烯酰甘氨酸を取り扱う際の実験室安全事項は何ですか？

1H,1H-全氟-3,6-二氧杂葵-1-醇を取り扱う際の実験室安全事項は何ですか？

3-(4-(フルオロメチルオキシ)フェニル)-1,2,4-オキサジアゾール-5-カルボハイドライドは安全ですか？

掲載誌

Chemical Communications

おすすめ化合物

N-(5-Bromo-2-hydroxyphenyl)acetamide

4-Bromo-5,7-difluoro-1H-indole

4-(Dimethylamino)-4'-fluorochalcone

2-Methyl-2-propanyl (2E)-5-chloro-2-[3-methoxy-4-(4-methyl-1H-imidazol-1-yl)benzylidene]pentanoate

N,N'-Bis[3-(2-methoxyphenyl)-2-hydroxybenzyl](1R,2R)-1,2-cyclohexanediamine

おすすめサプライヤー