Aluminyl derived ethene functionalization with heteroallenes, leading to an intramolecular ligand rearrangement

文献情報

出版日 2023-12-22

DOI 10.1039/D3CC05785B

インパクトファクター 6.222

著者

Andrea O’Reilly, Michael G. Gardiner, Claire L. McMullin, J. Robin Fulton, Martyn P. Coles

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要旨

The aluminacyclopropane K[Al(NON)(η-C2H4)] ([NON]2− = [O(SiMe2NDipp)2]2−, Dipp = 2,6-iPr2C6H3) reacts with CO2 and iPrNCNiPr to afford ring-expanded products of C–C bond formation. The latter system undergoes a 1,3-silyl retro-Brook rearrangement of the NON-group, to afford the [NNO]2− ligand ([NNO]2− = [N(Dipp)SiMe2N(Dipp)SiMe2O]2−). The mechanism of transformation was examined by density functional theory (DFT).

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Aluminyl derived ethene functionalization with heteroallenes, leading to an intramolecular ligand rearrangement

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