Non-classical (NC), heptagon-containing fullerenes obtained via chlorination-promoted cage transformations: C76(NC2a)Cl24 and C76(NC2b)Cl28

文献情報

出版日 2024-01-02

DOI 10.1039/D3CC05336A

インパクトファクター 6.222

著者

Victor A. Brotsman, Sergey I. Troyanov

原文を見る

要旨

High-temperature chlorination of C76 fullerene with SbCl5 proceeds via five Stone–Wales rearrangements, resulting in non-classical (NC) C76(NC1a)Cl24 with two heptagons and 14 pentagons partically fused in pairs and triples. C76(NC2b)Cl28 with isomeric carbon cage was obtained by chlorination-promoted cage shrinkage of C80via two C2 losses. The pathways of skeletal cage trasformations, the chlorination patterns, and formation energies are discussed in detail.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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