Polymerization of monomer aggregates for tailoring and patterning water wettability

文献情報

出版日 2023-12-04

DOI 10.1039/D3CC05172B

インパクトファクター 6.222

著者

Manideepa Dhar, Chittaranjan Mishra, Avijit Das

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要旨

An approach of 'polymerization of monomers in its aggregated form' is unprecedentedly introduced to (i) tailor the water wettability of fibrous and porous substrates from hydrophobicity to superhydrophobicity, and (ii) associate patterned wettability. A solution of selected monomers—i.e., alkyl acrylate in a good solvent (indicating high solubility; ethanol) was transferred into a bad solvent (refers to poor solubility; water) to achieve a stable dispersion of monomer aggregates of size <1 μm for deposition on fibrous and porous substrates. Its photopolymerization provided a durable coating with the ability to tailor the water wettability from 134° to 153°. Furthermore, a spatially selective photopolymerization process yielded a patterned interface of superhydrophilicity and superhydrophobicity. Such a facile chemical approach with the ability to provide a durable coating embedded with tailored and patterned wettability would be useful for various potential applications.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Polymerization of monomer aggregates for tailoring and patterning water wettability

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