Co-doped MoS2 nanosheet: a stable and pH-universal electrocatalyst for an efficient hydrogen evolution reaction
文献情報
Xiaojie Tan, Depeng Zhao, Yuchen Sun, Zhongxin Duan, Xiaowei Wang
Generally, the hydrogen generation of non-noble metal-based electrocatalysts is limited by the high overpotential and acid–base environment of electrolyte. Therefore, it is essential to develop hydrogen evolution reaction (HER) catalysts with high activity and a broad pH range. In this work, we report several Co-doped MoS2 nanosheet structures prepared by a simple hydrothermal approach. Co doping induces the interlayer expansion of MoS2 nanosheets. It not only increases the transfer pathways of electrolyte ions but also provides many active sites. Thereinto, Co0.4-MoS2 nanosheets show outstanding HER activity in a wide pH range. This facile synthesis strategy can be used to prepare other transition metal chalcogenide electrocatalysts.
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CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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