Tandem catalysis using an enzyme and a polymeric ruthenium-based artificial metalloenzyme

文献情報

出版日 2021-11-09

DOI 10.1039/D1PY01255J

インパクトファクター 5.582

著者

Edzna S. Garcia, Thao M. Xiong, Abygail Lifschitz, Steven C. Zimmerman

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要旨

A Ru-containing single chain nanoparticle (SCNP) was prepared in three steps using radical polymerization of pentafluorophenylacrylate, post-polymerization functionalization with three different alkylamines, and coordination of Ru. The polymer was characterized by 1H NMR, 19F NMR, UV-vis, and DLS. The catalytic activity of the Ru-SCNP for Ru-catalyzed cleavage of allylcarbamates was evaluated by fluorescence spectroscopy and a higher percent conversion and initial rate of reaction was observed when compared to that of the free catalyst in buffer and cell media. The catalytic SCNP was also shown to perform tandem catalysis with β-galactosidase.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Tandem catalysis using an enzyme and a polymeric ruthenium-based artificial metalloenzyme

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