Progress, challenges and future directions of heterocycles as building blocks in iterative methodologies towards sequence-defined oligomers and polymers

文献情報

出版日 2021-07-14

DOI 10.1039/D1PY00425E

インパクトファクター 5.582

著者

Stephen A. Hill, Robert Steinfort, Laura Hartmann

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要旨

The synthesis of sequence-defined oligomers and polymers is an important contemporary research topic due to the potential for creating materials with function tailored directly into the primary structure. Sequence-defined materials have so far been applied to biomimicry, data storage and sensing. Heterocyclic building blocks such as thiolactones and epoxides are key building blocks for producing sequence-defined macromolecules using iterative methodologies. In this review we critically evaluate: the current literature on different heterocyclic strategies using solid- or solution-phase methods for the iterative synthesis of sequence-defined polymers; the challenges surrounding these systems; and the potential future direction of heterocycles, so far not used in this field.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Progress, challenges and future directions of heterocycles as building blocks in iterative methodologies towards sequence-defined oligomers and polymers

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