Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes

文献情報

出版日 2020-12-30

DOI 10.1039/D0QO01465F

インパクトファクター 5.281

著者

Yan-Kai Huang, Wen-Zhen Zhang, Ke Zhang, Wen-Le Wang, Xiao-Bing Lu

原文を見る

要旨

1,3-Dienes are versatile synthons and important monomers. Herein we report a carbon dioxide promoted dehydration reaction of primary allylic alcohols to produce substituted 1,3-dienes in good yields. Taking advantage of carbon dioxide as a promoter to facilitate the alcoholic C–O bond cleavage via the formation of an allylic bicarbonate ester, this reaction proceeds under mild conditions.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes

文献情報

おすすめジャーナル

関連文献

Inside front cover

Spectroelectrochemical responses of thin-film conducting copolymers prepared electrochemically from mixtures of 3,4-ethylenedioxythiophene and 2,2′-bithiophene

Fourth-order coherent Raman spectroscopy in a time domain: applications to buried interfaces

Frequency-dependent response properties and excitation energies from one-electron density matrix functionals

Inside front cover

Contents

Binding free energy prediction in strongly hydrophobic biomolecular systems

Surface electrochemistry of CO as a probe molecule on carbon-supported Se-surface modified Ru nanoparticlesviainfrared reflection absorption spectroscopy

How realistic is the pore size distribution calculated from adsorption isotherms if activated carbon is composed of fullerene-like fragments?

Selected ion flow tube cation–molecule reaction studies and threshold photoelectron photoion coincidence spectroscopy of cyclic-C5F8

こちらもおすすめ

1-{3-[5-(エチルカルボンイル)-2,4-ジメチル-1H-ピロロール-3-基]プロパニル}ピペリジン-4-カルボン酸について、適用される法規ガイドラインは何ですか？

2,2-二氟-1,3-ベンゾジオキサン-5-カルボキシlic酸とは何ですか？

8-氯-4-色原酮の代替品はありますか？

エチル6,6-ジメチル-4,5,6,7-テトラヒドロ-1H-インドアゼー-3-カルボキシレートとは何ですか？

4-叔丁基-6-氯-嘧啶に適用される法規ガイドラインは何ですか？

維库溴铵杂质Bはどのように合成されますか？

2-(4-氟苄基)-吡咯烷の物理化学的性質は何ですか？

3-喹啉甲醛（2-チロール-8-エチル）は安全ですか？

エチル3-(ヒドロキシメチル)-1H-ピロール-2-カルボキシレートはどのように保存すればよいですか？

哌拉西林杂质Dは安全ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

Tris(2-ethylhexyl) 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate

2-Methyl-2-propanyl (2-aminoethyl)carbamate

1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate

3-[(4-Nitrobenzyl)oxy]-3-oxopropanoic Acid

1-Chloro-6,6-dimethyl-2-hepten-4-yne

おすすめサプライヤー