Surface electrochemistry of CO as a probe molecule on carbon-supported Se-surface modified Ru nanoparticlesviainfrared reflection absorption spectroscopy
文献情報
Elena R. Savinova, Francoise Hahn, Nicolas Alonso-Vante
The carbon monoxide molecule is used to probe the electronic properties of Ru/C and Se surface-modified Ru/C nanocatalysts. Coordination of a Se to a Ru surface strongly affects the vibrational properties and reactivity of the CO adsorbed. Marked alteration of the CO stretching frequency; increase of the Stark tuning rate for C–O vibration; and a positive shift of the onset of CO oxidation are observed for Se-modified Ru particles and attributed to the electronic effect of Se.
おすすめジャーナル

Heteroatom Chemistry

Biocatalysis and Biotransformation

Herald of the Russian Academy of Sciences

Bioorganic & Medicinal Chemistry

Bioorganic & Medicinal Chemistry Letters

Acta Metallurgica Sinica-English Letters

Journal of the Indian Institute of Science

Electroanalysis

Atomization and Sprays

Main Group Chemistry
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