Nickel-catalyzed enantioselective electroreductive cross-couplings

文献情報

出版日 2020-09-03

DOI 10.1039/D0QO00901F

インパクトファクター 5.281

著者

Zhijun Zhou, Sheng Xu, Jing Zhang, Wangqing Kong

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要旨

Ni-Catalyzed reductive cross-coupling of two electrophiles has recently evolved into a powerful means for building diverse carbon–carbon bonds in an enantioselective manner. However, this strategy usually requires the use of excessive metal powder as a reducing agent, which poses severe challenges with respect to reproducibility and sustainability. Electrochemical cathode reduction provides new opportunities for reductive cross-coupling reaction in an environmentally benign manner. In this highlight, we summarize the recent progress in Ni-catalyzed enantioselective electroreductive coupling reactions.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Nickel-catalyzed enantioselective electroreductive cross-couplings

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