Cascade cyclization versus chemoselective reduction: a solvent-controlled product divergence

文献情報

出版日 2020-09-08

DOI 10.1039/D0QO00876A

インパクトファクター 5.281

著者

Farnaz Jafarpour, Saideh Rajai-Daryasarei, Mohammad Hossein Gohari

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要旨

A simple and efficient strategy for the assembly of polysubstituted thiophenes and the chemoselective reduction of α,β-unsaturated ketones via the reaction of enones with elemental sulfur and by a simple switching of the reaction solvent is described. Mechanistic studies revealed that both the reactions proceeded via radical pathways, and two hydrogen atoms came from H2O in the reduction course.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Cascade cyclization versus chemoselective reduction: a solvent-controlled product divergence

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