Tellurophene-containing π-conjugated polymers with unique heteroatom–heteroatom interactions by post-element-transformation of an organotitanium polymer

文献情報

出版日 2020-07-07

DOI 10.1039/D0PY00724B

インパクトファクター 5.582

著者

Hiroki Nishiyama, Feng Zheng, Shinsuke Inagi, Hiroyuki Fueno, Ikuyoshi Tomita

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要旨

A unique π-conjugated polymer that possesses fully coplanar ring units through a tellurium–oxygen interaction, poly[(tellurophene-2,5-diyl)-alt-(2,5-dialkoxybenzene-1,4-diyl)], was prepared by the post-element-transformation of a titanacyclopentadiene-containing reactive precursor. The characteristic features of the heteroatom–heteroatom interaction and the electronic features of the polymer such as high HOMO and low LUMO energy levels are described.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Tellurophene-containing π-conjugated polymers with unique heteroatom–heteroatom interactions by post-element-transformation of an organotitanium polymer

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