Ring opening polymerization of macrocyclic oligoesters derived from renewable sources

文献情報

出版日 2020-03-17

DOI 10.1039/D0PY00258E

インパクトファクター 5.582

著者

Antxon Martínez de Ilarduya, Sebastián Muñoz Guerra

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要旨

Macrocyclic oligoesters (MCOs) derived from biomass such as those prepared from alkylene alkanedioates and 2,5-furandicarboxylates are suitable compounds for ring opening polymerization (ROP) to produce high molecular weight bio-based polyesters. The synthetic procedures that have been recently developed to obtain these MCOs in good yields, their ROP either alone or together with other cyclic compounds, and their recovery by cyclodepolymerization of the final polyesters are the main topics covered in this review. Both organometallic compounds and enzymes such as Candida antarctica lipase B are the catalytic systems used for all reactions. This synthetic approach based on ROP of MCOs derived from renewable sources opens a green pathway for a circular economy in plastics.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Ring opening polymerization of macrocyclic oligoesters derived from renewable sources

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