Photocatalytic oxygen evolution triggered by photon upconverted emission based on triplet–triplet annihilation
文献情報
Shutaro Tateyama, Fuminao Kishimoto
A visible light responsive photocatalyst, Mo-doped BiVO4 (Mo:BVO), was shown to promote oxygen evolution from water in response to photon upconverted emission based on triplet–triplet annihilation (TTA) in the same aqueous dispersion. Composites comprising a triplet sensitizer (Pt(II) octaethylporphyrin; PtOEP) and a singlet emitter (9,10-diphenylanthracene; DPA) intercalated in a layered clay compound (montmorillonite or saponite) were prepared using a facile but versatile solvothermal method. These composites were capable of converting green incident light (λ = 535 nm) to blue light (λ = 430 nm) even in air. The host layered clay as well as the co-intercalated surfactant evidently functioned as barriers against water and oxygen to prevent the quenching of the active compounds. The TTA upconversion driven photocatalytic oxygen evolution using the aqueous mixture of the dyes-clay composite and particulate photocatalysts can be a potential approach to eliminate the undesired optical losses and thus be a breakthrough for future industrial and large-scale installation in an inexpensive manner.
関連文献
Responses of polar organic compounds to different ionic environments in aqueous media are interrelated
L. A. Ferreira, A. Chervenak, S. Placko, A. Kestranek, P. P. Madeira, B. Y. Zaslavsky
DOI: 10.1039/C4CP02084G
Pyrene based conjugated materials: synthesis, characterization and electroluminescent properties
Jagadish K. Salunke, Prashant Sonar, F. L. Wong, V. A. L. Roy, C. S. Lee, Prakash P. Wadgaonkar
DOI: 10.1039/C4CP03693J
Realizing semiconductor–half-metal transition in zigzag graphene nanoribbons supported on hybrid fluorographene–graphane nanoribbons
Shaobin Tang, Xinrui Cao
DOI: 10.1039/C4CP03291H
Photoelectrochemical reduction of aqueous protons with a CuO|CuBi2O4 heterojunction under visible light irradiation
Hyun S. Park, Chong-Yong Lee, Erwin Reisner
DOI: 10.1039/C4CP03883E
Dynamic and thermodynamic characteristics associated with the glass transition of amorphous trehalose–water mixtures
Lindong Weng, Gloria D. Elliott
DOI: 10.1039/C3CP55418J
Characterization of C60 fullerene complexation with antibiotic doxorubicin
Yu. I. Prylutskyy, I. S. Pashkova, D. Wyrzykowski, A. Woziwodzka, G. Gołuński, J. Piosik, V. V. Cherepanov, U. Ritter
DOI: 10.1039/C4CP03367A
Light-driven microbial dissimilatory electron transfer to hematite
Dao-Bo Li, Yuan-Yuan Cheng, Ling-Li Li, Wen-Wei Li, Yu-Xi Huang, Dan-Ni Pei, Zhong-Hua Tong, Yang Mu, Han-Qing Yu
DOI: 10.1039/C4CP04065A
Ab initio Kinetic Monte Carlo simulations of dissolution at the NaCl–water interface
Peter Spijker, Nico Holmberg, Adam S. Foster
DOI: 10.1039/C4CP02375G
Capture of heliophobic atoms by 4He nanodroplets: the case of cesium
Antonio Leal, David Mateo, Alberto Hernando, Martí Pi, Manuel Barranco
DOI: 10.1039/C4CP03297G
Depletion region effect of highly efficient hole conductor free CH3NH3PbI3 perovskite solar cells
Sigalit Aharon, Shany Gamliel, Bat El Cohen, Lioz Etgar
DOI: 10.1039/C4CP00460D
こちらもおすすめ
3-イチチルビフェニルはどのように合成されますか?
3-イチチルビフェニルは、ビフェニルとイチプロピオニトリルを回収率約90%で反応させて合成されます。触媒は通常、亜リチウムホウ素を用います。
8-溴-5-三氟甲基喹啉はどのように合成されますか?
8-溴-5-三氟甲基喹啉は、5-トリフルオロメチル-2-メチル-1,3-ベンゼンジオールをブロモエタノールと反応させて生成します。この反応は塩基性条件下で行われ...
ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品はありますか?
ジメチル4-(4,4,5,5-テトラメチル-1,3,2-ドioxaborolan-2-基)-2,6-ピリジンジカルボイル酸フェニルアミニドの代替品としては、4-...
N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向や研究トレンドはどのようなものでしょうか?
N-(3,5-ヘキサクロロ-4-ピリドインイル)-8-メチオキシ-5-キノリンカーボン酸の市場動向は、主に産業用途での需要により影響を受けます。研究トレンドとし...
イソステアロイルグリセリルは安全ですか?
イソステアロイルグリセリルは一般的に安全性が高いとされていますが、過度な使用や個人差により皮�owsん炎などの反応が起こる可能性があります。使用前に医師に相談す...
1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向や研究トレンドはどうですか?
1-(二苯甲基)-3,3-二氟-氮杂环丁烷の市場動向は、医薬品や合成化学の研究分野で注目を集めています。新興研究は、該当化合物の合成改良と生体内での作用メカニズ...
3-チオフェンスチオールの物理化学的性質は何ですか?
3-チオフェンスチオールのCAS番号は7774-73-4です。結晶性の白色粉末で、分子量は122.17です。この化合物は水に微溶解し、エタノールやジクロロメタン...
2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは安全ですか?
2-Methyl-2-propanyl (2S)-2-(aminomethyl)-1-piperidinecarboxylateは一定の安全性基準を満たしていま...
CAS番号1316822-90-8の化合物は安全ですか?
CAS番号1316822-90-8の化合物は安全性に関しては評価が不足していますが、一般的には生物学的に活性な物質であり、取り扱いには適切な安全防護措置が必要で...
Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸はどのように保存すればよいですか?
Tert-butyl 2-(2-羟基乙基)哌嗪-1-羧酸は、冷暗所で保存し、直射日光から遠ざけてください。容器は密閉し、高湿度や高温を避けて保管してください。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![N-{15-[(2,5-Dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}-2-(2-propyn-1-yloxy)acetamide structure N-{15-[(2,5-Dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}-2-(2-propyn-1-yloxy)acetamide structure](https://static.chemtradehub.com/structs/210/2101206-92-0-2eb5.webp)

![1-(1-Benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-benzo[d]imidazol-2(3H)-one structure 1-(1-Benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-benzo[d]imidazol-2(3H)-one structure](https://static.chemtradehub.com/structs/603/60373-71-9-7dfb.webp)

