Investigating the effects of pyridine and poly(4-vinylpyridine) on CO2 reduction electrocatalysis at gold electrodes using in situ surface-enhanced Raman spectroelectrochemistry
文献情報
The CO2 reduction reaction (CO2RR) at metal electrodes is altered in the presence of pyridine and related species. Thick films of poly(4-vinylpyridine) on Au electrodes result in large current enhancements at low applied potentials but do not enhance CO2RR at these potentials. Surface-enhanced Raman spectroelectrochemistry can probe CO2-surface interactions and reveals that desorption of CO2 as bicarbonate is retarded in the presence of 4-PVP, with implications for ion-transport limitations in thick film CO2RR.
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phosphoryl}methyl 4-methylbenzenesulfonate structure {[3-(Hexadecyloxy)propoxy](hydroxy)phosphoryl}methyl 4-methylbenzenesulfonate structure](https://static.chemtradehub.com/structs/864/864068-45-1-ba7c.webp)
