Exploring the charge reactions in a Li–O2 system with lithium oxide cathodes and nonaqueous electrolytes
文献情報
Rachid Amine, Xuanxuan Bi, Yan Qin, Matthew Li, Said Al-Hallaj, Fengwei Huo, Jun Lu, Khalil Amine
Nonaqueous lithium–oxygen batteries have attracted considerable attention due to their high energy density. Huge efforts have been made to unravel the fundamentals of Li–O2 battery chemistry. However, current Li–O2 batteries still suffer from several unresolved problems such as the instability of electrolytes and sluggish oxidation of lithium oxides during the charging process. In this work, we propose a detailed study to investigate the charge mechanism of lithium oxide materials in different electrolytes. Commercially available lithium peroxide and lithium oxide have been employed as cathodes to determine how lithium oxides (both lithium oxide and lithium peroxide) and electrolytes change during charge. The result shows that Li2O2 decomposed to lithium and oxygen; meanwhile, the electrolyte has a significant influence on Li2O2 decomposition. Furthermore, while most of the Li2O material participates in side reactions with the electrolyte, some of it is found to delithiate and crumble in structure.
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Journal of Materials Chemistry A

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment










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