Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor

文献情報

出版日 2019-04-17

DOI 10.1039/C9RE00061E

インパクトファクター 4.239

著者

Eiji Yamaguchi, Nao Taguchi, Akichika Itoh

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要旨

Previously, we reported the ruthenium polypyridyl complex-catalysed aryl alkoxylation reaction of styrenes with aryldiazonium salts. In the developed reaction course, the instability of the diazonium salts caused poor product yields. In this context, we focused on the use of a continuous flow photo microreactor as a way to improve the efficacy of the aryl alkoxylation reaction. In this report, we describe an improved protocol for the aryl alkoxylation of styrenes catalysed by a ruthenium polypyridyl complex that relies on the use of a continuous flow photo microreactor.

掲載誌

Reaction Chemistry & Engineering

CiteScore: 0

自己引用率: 8.8%

年間論文数: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor

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