Rh-Catalyzed C–C/C–N bond formation via C–H activation: synthesis of 2H-indazol-2-yl-benzo[a]carbazoles

文献情報

出版日 2019-10-14

DOI 10.1039/C9QO01120J

インパクトファクター 5.281

著者

Sundaravel Vivek Kumar, Sonbidya Banerjee, Tharmalingam Punniyamurthy

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要旨

Rh-Catalyzed tandem site-selective C–H activation and ring opening/cyclization of 7-azabenzonorbornadienes with aryl-2H-indazoles is developed to furnish indazolyl-benzocarbazoles. The mechanistic studies suggest that the second C–H activation is the product-determining step. The use of an air stable cationic Rh-catalyst and site-selectivity, and substrate scope are the important practical features.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Rh-Catalyzed C–C/C–N bond formation via C–H activation: synthesis of 2H-indazol-2-yl-benzo[a]carbazoles

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