Rh(i)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

文献情報

出版日 2019-04-03

DOI 10.1039/C9QO00343F

インパクトファクター 5.281

著者

Kang-Hua Rui

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要旨

A cationic Rh(I) complex-catalyzed intramolecular [3 + 2] cycloaddition reaction of newly developed yne-vinylidenecyclopropanes (VDCPs) has been established, affording an efficient synthesis of fused [6.5]-bicyclic structures in moderate to good yields under mild conditions. Moreover, the reaction exhibits a broad substrate scope along with good functional group tolerance.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Rh(i)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

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