Effects of temperature and pressure on the optical and vibrational properties of thermoelectric SnSe
文献情報
Ilias Efthimiopoulos, Matthias Berg, Annika Bande, Ljiljana Puskar, Eglof Ritter, Wei Xu, Michele Ortolani, Martin Harms, Jan Müller, Sergio Speziale, Monika Koch-Müller, Yong Liu, Li-Dong Zhao, Ulrich Schade
We have conducted a comprehensive investigation of the optical and vibrational properties of the binary semiconductor SnSe as a function of temperature and pressure by means of experimental and ab initio probes. Our high-temperature investigations at ambient pressure have successfully reproduced the progressive enhancement of the free carrier concentration upon approaching the Pnma → Bbmm transition, whereas the pressure-induced Pnma → Bbmm transformation at ambient temperature, accompanied by an electronic semiconductor → semi-metal transition, has been identified for bulk SnSe close to 10 GPa. Modeling of the Raman-active vibrations revealed that three-phonon anharmonic processes dominate the temperature-induced mode frequency evolution. In addition, SnSe was found to exhibit a pressure-induced enhancement of the Born effective charge. Such behavior is quite unique and cannot be rationalized within the proposed effective charge trends of binary materials under pressure.
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