Trimerization and tetramerization of ethylene in continuous gas-phase reaction using a Cr-based supported liquid phase catalyst

文献情報

出版日 2018-11-19

DOI 10.1039/C8RE00179K

インパクトファクター 4.239

著者

Tobias Müller, John Thomas Dixon, Marco Haumann, Peter Wasserscheid

原文を見る

要旨

Homogeneous Cr–PNP tri- and tetramerization catalysts were dissolved together with the co-catalyst MAO in the high-boiling, non-polar, aliphatic hydrocarbon perhydro-dibenzyltoluene (H18-DBT). The solution was then dispersed onto different high surface area supports. The resulting solid materials were tested in the gas-phase selective oligomerization of ethylene at 43 °C and pressures between 1 and 14 bar. Low activities were observed at ambient pressure. At ethylene pressures of higher than 3 bar the formed 1-hexene and 1-octene condensed inside the porous system, thereby facilitating the dissolution and redistribution of the Cr–PNP catalyst. Further studies were conducted at pressures up to 35 bar at which a change in the primary reaction selectivity from 1-hexene to 1-octene could be observed. Such a selectivity switch is in accordance with previously reported mechanistic and kinetic studies.

掲載誌

Reaction Chemistry & Engineering

CiteScore: 0

自己引用率: 8.8%

年間論文数: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

Trimerization and tetramerization of ethylene in continuous gas-phase reaction using a Cr-based supported liquid phase catalyst

文献情報

おすすめジャーナル

関連文献

Dendrimer design using CuI-catalyzed alkyne–azide “click-chemistry”

99m-Technetium carbohydrate conjugates as potential agents in molecular imaging

Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite

Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of TiNNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

Crystallographic characterization and identification of a minor isomer of C84fullerene

Glucose production from saccharides using layered transition metal oxide and exfoliated nanosheets as a water-tolerant solid acid catalyst

Greatly reduced amino acid alphabets in directed evolution: making the right choice for saturation mutagenesis at homologous enzyme positions

One-pot solvothermal synthesis of FePt/Fe3O4 core–shell nanoparticles

Sonication treatment of CdTe/CdS semiconductor nanocrystals and their bio-application

A general precipitation strategy for large-scale synthesis of molybdate nanostructures

こちらもおすすめ

S-(甲硅烷基丙基)異硫酰氯を取り扱う際の実験室安全事項は何ですか？

8-硝基-咪唑并[1,2-a]吡啶とは何ですか？

4-ブロモ-5-メトキシピリジン-2-甲醇の代替品はありますか？

全氟-1,2-二甲基環己烷を含む廃棄物はどのように処理すべきですか？

3-(溴甲基)苯乙酸の主な用途は何ですか？

5-イドキド-4-メチオキシ-6-メチルピリミジニン-2-アミンはどのように保存すればよいですか？

1-(2-溴-6-甲氧基苯基)乙酮を取り扱う際の実験室安全事項は何ですか？

5-(4,4,5,5-テトラメチル-1,3,2-ダイオキサボラロール-2-イル)-1,3-ジヒドロ-2-ベンゾフランは安全ですか？

4-溴萘-1-甲酸の代替品はありますか？

ε-白藜芦醇脱氢二聚体の代替品はありますか？

掲載誌

Reaction Chemistry & Engineering

おすすめ化合物

Peptide YY

4,5,6,7-Tetrahydro-2H-indazole

Methyl 5-bromo-2-fluorobenzoate

(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid

4-Penten-1-yl 2-[(2-furylmethyl)(1H-imidazol-1-ylcarbonyl)amino]butanoate

おすすめサプライヤー