A NaSO2CF3/NaBrO3-mediated bromotrifluoromethylation of enyne via free-radical cascade processes

文献情報

出版日 2018-08-30

DOI 10.1039/C8QO00847G

インパクトファクター 5.281

著者

Xiao-Jie Shang, Dong Liu, Zhong-Quan Liu

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要旨

A NaBrO3-triggered free radical bromotrifluoromethylation of enynes with NaSO2CF3 was developed. It provides a facile access to a wide range of bromotrifluoromethylated five- and six-membered heterocycles. A spin trapping experiment together with electron spin resonance (ESR) studies indicated it should be conducted through a free radical process.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

A NaSO2CF3/NaBrO3-mediated bromotrifluoromethylation of enyne via free-radical cascade processes

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