Hydrofunctionalization of alkenols triggered by the addition of diverse radicals to unactivated alkenes and subsequent remote hydrogen atom translocation

文献情報

出版日 2018-08-22

DOI 10.1039/C8QO00734A

インパクトファクター 5.281

著者

Liu Ye, Zhong-Liang Li, Lei Li, Zhuang Li, Hong-Xia Zhang, Zhen Guo, Qiang-Shuai Gu, Xin-Yuan Liu

原文を見る

要旨

Diverse anti-Markovnikov hydrofunctionalization of alkenols triggered by the addition of S-, P-, and C-centered radicals to alkenes followed by intramolecular 1,5(6)-hydrogen atom transfer (HAT) with remote α-C–H bonds of alcohols has been developed. The strategy simultaneously realized the hydrofunctionalization of alkenes and remote alcohol oxidation. This mild and versatile method allows for direct access to valuable sulfonyl-, phosphonyl-, and malonate-substituted ketones or aldehydes from a wide range of alkenols.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Hydrofunctionalization of alkenols triggered by the addition of diverse radicals to unactivated alkenes and subsequent remote hydrogen atom translocation

文献情報

おすすめジャーナル

関連文献

A step out of the lab and into the field: a giant leap from technology to capability

Factors influencing the discrimination and classification of prostate cancer cell lines by FTIR microspectroscopy

Enzyme-catalyzed signal amplification for electrochemical DNA detection with a PNA-modified electrode

Empirical versus modelling approaches to the estimation of measurement uncertainty caused by primary sampling

Measuring complexation by single-molecule fluorescence anisotropy

In-capillary enrichment, proteolysis and separation using capillary electrophoresis with discontinuous buffers: application on proteins with moderately acidic and basic isoelectric points

A review of biosensors and biologically-inspired systems for explosives detection‡

Analysis of DNA and single-base mutations using magnetic particles for purification, amplification and DNAzyme detection

José Pingarrón, Complutense University of Madrid, Spain

Peptide microarrays for carbohydrate recognition

こちらもおすすめ

4'-ブロモビフェニル-3-メトークシーディ.ActionBarはどのように保存すればよいですか？

間甲苯乙腈とは何ですか？

2-異丙基フェニルヒドラジン塩酸塩とは何ですか？

5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンを取り扱う際の実験室安全事項は何ですか？

去甲基雷贝拉唑硫醚はどのように合成されますか？

2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは安全ですか？

対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚の物理化学的性質は何ですか？

2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環はどのように保存すればよいですか？

6-アミノ-5-クロロ-2-シクロプロピルピリミジンカルボン酸の代替品はありますか？

5-クロロベンゾ[1,3]二オキセイン-4-アミンに適用される法規ガイドラインは何ですか？

掲載誌

Organic Chemistry Frontiers

おすすめ化合物

(3S,4aS,8aS)-2-[(2R,3S)-3-Amino-2-hydroxy-4-phenylbutyl]-N-(2-methyl-2-propanyl)decahydro-3-isoquinolinecarboxamide

2-Hydroxy-5-iodo-4-methylbenzoic acid

25-Deacetyl-23-acetyl RifaMpicin

3-Methoxy-1-piperidinamine

(2,2-Diethoxyethyl)(3-methoxyphenyl)sulfane

おすすめサプライヤー