Functional polyamides with gem-diazido units: synthesis and diversification

文献情報

出版日 2018-11-09

DOI 10.1039/C8PY01087K

インパクトファクター 5.582

著者

Phillip Biallas, Janina Heider, Stefan F. Kirsch

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要旨

A diazidated malonate derivative was employed as a monomer for the reagent-free one-pot synthesis of several polyamides containing geminal diazido moieties within the polymer backbone. Using different diamines, azide-rich polyamides with diverse properties and sensitivities dependent on the structure of the diamine units were obtained. Postpolymerization CuAAC reactions of the geminal diazido units in the polymer backbone allowed for the introduction of additional functionalities, and the construction of densely functionalized polymeric structures.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Functional polyamides with gem-diazido units: synthesis and diversification

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