Unexpected formation of [5]helicenes from hexaarylbenzenes containing pyrrole moieties

文献情報

出版日 2017-03-23

DOI 10.1039/C7QO00112F

インパクトファクター 5.281

著者

Felix Ammon, Stephanie Theresia Sauer, Rainer Lippert, Dominik Lungerich, David Reger, Frank Hampel, Norbert Jux

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要旨

A synthetic route to hexaarylbenzenes containing up to six pyrrole units was developed. These pyrrole moieties are connected to the central benzene core via their β-carbon atom. Oxidative cyclodehydrogenation of systems containing one pyrrole ring led to the formation of [5]helicenes instead of the completely fused coronene-like structure.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Unexpected formation of [5]helicenes from hexaarylbenzenes containing pyrrole moieties

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