The terpolymerization of ethylene and propylene with isoprene via THF-containing half-sandwich scandium catalysts: a new kind of ethylene–propylene–diene rubber and its functionalization

文献情報

出版日 2017-06-26

DOI 10.1039/C7PY00847C

インパクトファクター 5.582

著者

原文を見る

要旨

The terpolymerization of ethylene and propylene with isoprene was performed catalyzed by half-sandwich scandium complexes (C5Me4SiMe3)Sc(CH2SiMe3)2(THF) (1) and [1,3-(Me2Si)2C9H5]Sc(CH2SiMe3)2 (THF) (2) in combination with 1 equiv. of [Ph3C][B(C6F5)4]. The terpolymers with ethylene contents of 60–84 mol% and isoprene contents of 5–26 mol% (1,4/3,4 ≈ 50/50) were obtained in the presence of complex 1. In comparison, the terpolymers with ethylene contents of 38–75 mol% and isoprene contents of 4–43 mol% (1,4/3,4 ≈ 70/30) were obtained in the presence of complex 2. Subsequently, a functionalized ethylene–propylene–isoprene terpolymer was prepared by the epoxidation of the 1,4-isoprene units in the terpolymer backbone and further hydroxylation/chlorination through ring-opening reaction of the epoxy groups.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

The terpolymerization of ethylene and propylene with isoprene via THF-containing half-sandwich scandium catalysts: a new kind of ethylene–propylene–diene rubber and its functionalization

文献情報

おすすめジャーナル

関連文献

Back cover

Well-defined polyethylene-based graft terpolymers by combining nitroxide-mediated radical polymerization, polyhomologation and azide/alkyne “click” chemistry

A simple route to deuterated polystyrene block copolymers by reverse iodine transfer polymerisation

POSS-induced enhancement of mechanical strength in RAFT-made thermoresponsive hydrogels

A new pathway towards polymer modified cellulose nanocrystals via a “grafting onto” process for drug delivery

Synthesis of polysarcosine from air and moisture stable N-phenoxycarbonyl-N-methylglycine assisted by tertiary amine base

Pyrrolo[3,4-g]quinoxaline-6,8-dione-based conjugated copolymers for bulk heterojunction solar cells with high photovoltages

A macrocyclic oligoelectrolyte as a facial platform for absorbing hyaluronic acid oligomers for targeted cancer cellular imaging

Synthesis and properties of stimuli-sensitive heterografted toothbrush-like terpolymers with a linear handle and two types of V-shaped grafts

Facile anionic synthesis of a well-controlled thermally cross-linkable block copolymer for polymer-based resistive memory device applications

こちらもおすすめ

除水剤ALT-201は安全ですか？

「邻羟基阿托伐他汀内酯标准品」に適用される法規ガイドelinesは何ですか？

メチル（3R）-3-アミノ-2,3-ジヒドロ-1-ベンゾファンラニン-5-カルボイル酸塩塩酸塩の主な用途は何ですか？

トランス-4-メチルピロリジン-3-オール塩酸塩はどのように合成されますか？

硫雜環丁烷-1,1-二氧化物は安全ですか？

ブラエリリンの主な用途は何ですか？

9-ヒドロキシエリプチシネ塩酸塩はどのように合成されますか？

5-塩素-2-(メチルアミノ)フェニル-(2-塩素フェニル)メタン酮の物理化学的性質は何ですか？

1-[2-(4-甲氧基-苯氧基)-乙基]-哌嗪はどのように保存すればよいですか？

2-[3-(4-甲氧基フェニル)プロピル]-4,4,5,5-四メチル-1,3,2-ドイボロロールアンの主な用途は何ですか？

掲載誌

Polymer Chemistry

おすすめ化合物

6-Bromo-3,4-dihydro-2H-1,4-benzoxazine hydrochloride (1:1)

(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid

1-Methoxycyclopentene

1-(4-Methyl-2-thienyl)methanamine

2-Fluoro-4-(3-methylphenyl)benzoic acid

おすすめサプライヤー