ATRP mediated encapsulation of Gibbsite: fixation of the morphology by using a cross-linker

文献情報

出版日 2017-04-24

DOI 10.1039/C7PY00226B

インパクトファクター 5.582

著者

Olessya P. Loiko, Anne B. Spoelstra, Jan Meuldijk, Johan P. A. Heuts

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要旨

Using ethylene glycol dimethacrylate (EGDMA) as a cross-linker Gibbsite platelets were successfully encapsulated fully using an ATRP-mediated emulsion polymerisation technique. Previously we reported a “muffin-like” morphology, which was obtained using the same approach without a cross-linker. This morphology was attributed to the mobility of the growing polymeric chains, allowing them to move one side of the platelet during the reaction. The addition of EGDMA reduces this mobility and it is shown that this approach indeed leads to encapsulated Gibbsite. A comprehensive study of the reaction conditions, in particular the cross-linker addition profile and concentration, was carried out in combination with cryo-TEM characterization of the final particle morphology.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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ATRP mediated encapsulation of Gibbsite: fixation of the morphology by using a cross-linker

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