Inducing chemical reactivity on specific sites of a molecule using the Coulomb interaction exerted by a low energy electron

文献情報

出版日 2018-01-17

DOI 10.1039/C7CP08496J

インパクトファクター 3.676

著者

Y. Sajeev

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要旨

Remarkable site-specificity in the resonant attachment of low energy electrons (LEEs) to molecular targets is proposed as an efficient method for inducing chemical reactivity on specific sites of molecules. The Coulomb interaction between the attached electron and the most polarizable molecular electrons localized on the attached site is the reason for site-specific chemical reactivity. The Coulombically induced site-specific chemical reactivity is best illustrated by the LEE induced chemical transformation of a weakly bound molecular complex into a strong covalent adduct. The chemical transformation occurs due to the Coulombically induced nucleophilicity on a specific molecular moiety in the complex. A simple strategy for inducing site-specific chemical reactivity using a LEE may find new avenues in chemical synthesis.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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