Ultra-broadband EPR spectroscopy in field and frequency domains
文献情報
D. Bloos, R. Marx, P. Lutz, M. Kern, O. Laguta, C. Dietrich, J. van Slageren
Electron paramagnetic resonance (EPR) is a powerful technique to investigate the electronic and magnetic properties of a wide range of materials. We present the first combined terahertz (THz) field and frequency domain electron paramagnetic resonance (HFEPR/FDMR) spectrometer designed to investigate the electronic structure and magnetic properties of molecular systems, thin films and solid state materials in a very broad frequency range of 85–1100 GHz. In this paper, we show high resolution frequency-field (Zeeman) maps (170–380 GHz by 0–15 T) recorded on two single-molecule magnets, [Mn2(saltmen)2(ReO4)2] and [Mn2(salpn)2(H2O)2](ClO4)2, which give direct access to the field-dependence of the energy level diagram. Furthermore, supression of standing waves in the described system and the sensitivity in field and frequency domain operations is evaluated and discussed.
関連文献
Retinol initiated poly(lactide)s: stability upon polymerization and nanoparticle preparation
Diana Kalden, Matthias Westerhausen
DOI: 10.1039/C7PY00881C
A supramolecular peptide polymer from hydrogen-bond and coordination-driven self-assembly
Xiaomin Zhu, Rongfeng Zou, Peng Sun, Qi Wang, Junchen Wu
DOI: 10.1039/C7PY01901G
Development of liquid crystalline polyurethane composites with stage-responsive shape memory effects
Shaojun Chen, Jianfeng Ban, Luona Mu, Haitao Zhuo
DOI: 10.1039/C7PY01913K
Elaboration of bio-epoxy/benzoxazine interpenetrating polymer networks: a composition-to-morphology mapping
P. Verge, S. Peralta, Y. Habibi, C. Vancaeyzeele, F. Vidal
DOI: 10.1039/C7PY01755C
Reporting pH-sensitive drug release via unpaired spin fluorescence silencing
Bettina Olshausen, Kathryn E. Fairfull-Smith, Ute Schepers
DOI: 10.1039/C7PY01942D
A family of linear phenolic polymers with controlled hydrophobicity, adsorption and antioxidant properties
Raman Hlushko, Hanna Hlushko, Svetlana A. Sukhishvili
DOI: 10.1039/C7PY01973D
A sustainable photocontrolled ATRP strategy: facile separation and recycling of a visible-light-mediated catalyst fac-[Ir(ppy)3]
Xiaodong Liu, Yuanyuan Ni, Jian Wu, Hongjuan Jiang, Zhengbiao Zhang, Lifen Zhang, Zhenping Cheng
DOI: 10.1039/C7PY02008B
Preparation of graphene/poly(2-acryloxyethyl ferrocenecarboxylate) nanocomposite via a “grafting-onto” strategy
Yan Deng, Wenbin Liu, Yongjun Li, Xiaoyu Huang
DOI: 10.1039/C7PY01932G
こちらもおすすめ
2-ブロモ-9,9-ジフェニル-9H-フルオレンの主な用途は何ですか?
2-溴-9,9-二苯基芴は、医薬品、工業材料、有機合成の研究分野で応用されます。特に、レーザー材料や機能性ポリマーの合成に使用されることがあります。また、蛍光色...
四氯化铱の市場動向や研究トレンドはどうですか?
四氯化铱の市場は研究開発分野で注目されており、特にナノ技術や金属有機框架(MOFs)の分野での需要が増加傾向にあります。価格は安定しており、中国や韓国での生産が...
1-(4-溴-3-氟苯基)-2-氯乙酮を含む廃棄物はどのように処理すべきですか?
1-(4-溴-3-氟苯基)-2-氯乙酮 (CAS番号: 1260857-14-4) の廃棄物は専門的な廃棄処理が必要です。まず、廃棄物は密閉された容器に収集し、...
苦参酚Kとは何ですか?
苦参酚Kは、CAS番号101236-49-1を持つ化合物で、主に天然由来の生薬から抽出されます。この化合物は、抗炎症作用や抗癌作用を持つことが報告されています。
POTASSIUM (1-(TERTBUTOXYCARBONYL)AZETIDIN-3-YL)TRIFLUOROBORATE を含む廃棄物はどのように処理すべきですか?
POTASSIUM (1-(TERTBUTOXYCARBONYL)AZETIDIN-3-YL)TRIFLUOROBORATE を含む廃棄物は、まず安全なエント...
4-庚基-4’-联苯羧酸の市場動向や研究トレンドはどうですか?
4-庚基-4’-聯苯羧酸は、特殊化学品や合成化学の分野で用いられる化学物質ですが、市場動向としては、研究開発の進展とともに需要が増加しています。また、環境配慮型...
6-ブロモ-3-メトキシ-1-フェニル-1H-インドゾールを含む廃棄物はどのように処理すべきですか?
6-ブロモ-3-メトキシ-1-フェニル-1H-インドゾールを含む廃棄物は、適切な化学廃棄処理が必要です。通常、廃棄物は密閉容器に収集され、専門の廃棄処理業者に引...
4,4-二甲基-2-吡咯烷酮はどの業界で使用されていますか?
4,4-二甲基-2-吡咯烷酮は医薬、ポリマー、センサー、半導体などの業界で広く使用されています。特に溶媒としての性能が高く評価されています。
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














