Melting kinetics of superheated crystals of glucose and fructose
文献情報
Tatsiana Liavitskaya, Lily Birx, Sergey Vyazovkin
Glucose and fructose crystals undergo significant superheating during melting that allows one to study the kinetics of this process. Melting of both compounds has been studied by differential scanning calorimetry (DSC). The obtained data have been subjected to isoconversional kinetic analysis. The process has been determined to have unusually large values of the activation energy and preexponential factor that indicate that melting occurs by cooperatively breaking multiple hydrogen bonds. The experimentally determined activation energy of melting demonstrates a decrease with increasing temperature. The use of the nucleation and growth models has permitted deriving theoretical dependencies of the activation energy on temperature. Testing the theoretical dependencies against the experimental ones suggests that from either the statistical or physical viewpoint the melting kinetics should be parameterized by means of the growth model. This suggests that the mechanism of melting involves the growth of the stable melt nuclei that exist on the crystal surface below the equilibrium melting temperature.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
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