Dynamics of ethyl cellulose nanoparticle self-assembly at the interface of a nematic liquid crystal droplet
文献情報
Yining Han, Navid Bizmark, Marios A. Ioannidis
Design and fabrication of many next-generation liquid crystal (LC)-based devices rely on nematic LC domains in the form of drops or emulsions. In addition to surfactants, solid nanoparticles may be used to stabilize LC-in-water Pickering emulsions, possibly adding new dimensions to device functionality. In this work we quantitatively study the adsorption of ethyl cellulose (EC) nanoparticles, as a colloid model system, on the 4-cyano-4′-pentylbiphenyl (5CB)–water interface via a series of dynamic interfacial tension measurements. It is found that the planar alignment of 5CB molecules at the interface with water is unaffected by particle adsorption, but a significant reduction of the interfacial tension over time occurs. It is also found that adsorption of EC nanoparticles to the LC–water interface is irreversible and results in close hexagonal packing. This study demonstrates a systematic approach to quantitatively investigate the effect of nanoparticles on the stabilization of LC emulsions.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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