Single-photon Coulomb explosion of methanol using broad bandwidth ultrafast EUV pulses
文献情報
Itamar Luzon, Krishna Jagtap, Ester Livshits, Oleg Lioubashevski, Roi Baer, Daniel Strasser
Single-photon Coulomb explosion of methanol is instigated using the broad bandwidth pulse achieved through high-order harmonics generation. Using 3D coincidence fragment imaging of one molecule at a time, the kinetic energy release (KER) and angular distributions of the products are measured in different Coulomb explosion (CE) channels. Two-body CE channels breaking either the C–O or the C–H bonds are described as well as a proton migration channel forming H2O+, which is shown to exhibit higher KER. The results are compared to intense-field Coulomb explosion measurements in the literature. The interpretation of broad bandwidth single-photon CE data is discussed and supported by ab initio calculations of the predominant C–O bond breaking CE channel. We discuss the importance of these findings for achieving time resolved imaging of ultrafast dynamics.
おすすめジャーナル

Herald of the Russian Academy of Sciences

Journal of Chemical Sciences

NDT & E International

Bioorganic & Medicinal Chemistry

Electroanalysis

Polycyclic Aromatic Compounds

Biocatalysis and Biotransformation

Critical Reviews in Solid State and Materials Sciences

Main Group Chemistry

Journal of the Indian Institute of Science
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.


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