From tetrabenzoheptafulvalene to sp2 carbon nano-rings

文献情報

出版日 2017-01-13

DOI 10.1039/C6QO00828C

インパクトファクター 5.281

著者

Kwan Yin Cheung, Shuaijun Yang, Qian Miao

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要旨

Herein we report a new strategy to construct nano-rings of sp2 carbon by taking advantage of the “C” shape of syn-tetrabenzoheptafulvalene. This strategy led to the successful synthesis of an sp2 carbon nano-ring containing a tetrabenzoheptafulvalene moiety fused with tetraphenylene. However, attempts to synthesize a more strained nano-ring of sp2 carbon using the same strategy only yielded an oxygen-bridged nano-ring with the step of aromatization being unsuccessful. Both the nano-rings were unambiguously characterized by X-ray crystallography.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

From tetrabenzoheptafulvalene to sp2 carbon nano-rings

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