Pressure-induced emission band separation of the hybridized local and charge transfer excited state in a TPE-based crystal

文献情報

出版日 2018-04-28

DOI 10.1039/C8CP02096E

インパクトファクター 3.676

著者

Xuedan Liu, Aisen Li, Weiqing Xu, Zhiyong Ma, Xinru Jia

原文を見る

要旨

We herein report a newly synthesized simple molecule, named TPEC4, with twisted D–A structure. TPEC4 showed two intrinsic emission bands ascribed to the locally excited (LE) state and the intramolecular charge transfer (ICT) state, respectively. In the crystal state, the LE emission band is usually observed. However, by applying hydrostatic pressure to the powder sample and the single crystal sample of TPEC4, dual-fluorescence (445 nm and 532 nm) was emerged under high pressure, owing to the pressure-induced emission band separation of the hybridized local and charge transfer excited state (HLCT). It is found that the emission of TPEC4 is generally determined by the ratio of the LE state to the ICT state. The ICT emission band is much more sensitive to the external pressure than the LE emission band. The HLCT state leads to a sample with different responsiveness to grinding and hydrostatic pressure. This study is of significance in the molecular design of such D–A type molecules and in the control of photoluminescence features by molecular structure. Such results are expected to pave a new way to further understand the relationship between the D–A molecular structure and stimuli-responsive properties.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

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