Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions

文献情報

出版日 2017-01-03

DOI 10.1039/C6QO00730A

インパクトファクター 5.281

著者

Dong Li

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要旨

A highly site-selective oxidative C–H sulfonylation method for 8-acylaminoquinolines and anilides with sulfonyl chlorides has been developed, which provided C5-sulfonylated quinolines and para-sulfonylated anilides respectively. Good functional group compatibility was showed in both amides and sulfonyl substrates. This method was only mediated by using a hypervalent iodine reagent PhI(OPiv)2 under mild conditions without any metallic catalyst or extra additives, which would provide a novel and facile methodology for synthesis of sulfone compounds.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions

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