A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

文献情報

出版日 2016-11-08

DOI 10.1039/C6PY01844K

インパクトファクター 5.582

著者

Hui-Chun Lee, Markus Antonietti, Bernhard V. K. J. Schmidt

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要旨

A Cu(II) MOF can serve as an efficient catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP), e.g. for the synthesis of poly(benzyl methacrylate) (PBzMA) and polystyrene (PS). Furthermore, poly(isoprene) (PI) and poly(4-vinylpyridine) (P4VP) can be formed in a controlled fashion as well, which used to be challenging to achieve by traditional strategies. Taking advantage of the heterogeneous nature of the catalyst, recycling via centrifugation and repeated utilization for at least six cycles are demonstrated.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

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