Aqueous RAFT at pH zero: enabling controlled polymerization of unprotected acyl hydrazide methacrylamides

文献情報

出版日 2016-10-17

DOI 10.1039/C6PY01563H

インパクトファクター 5.582

著者

Emily A. Hoff, Brooks A. Abel, Chase A. Tretbar, Charles L. McCormick, Derek L. Patton

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要旨

We report aqueous RAFT polymerization at pH = 0 mediated by a novel imidazolium-containing chain transfer agent. In 1 M HCl, unprecedented controlled polymerization and chain-extension of unprotected acyl hydrazide methacrylamides is achieved enabling the synthesis of well-defined acyl hydrazide functionalized polymer scaffolds of interest for dynamic covalent and bioconjugation strategies.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Aqueous RAFT at pH zero: enabling controlled polymerization of unprotected acyl hydrazide methacrylamides

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