Alkyl substituted poly(p-phenylene vinylene)s by ring opening metathesis polymerisation

文献情報

出版日 2016-08-18

DOI 10.1039/C6PY01186A

インパクトファクター 5.582

著者

Benjamin J. Lidster, Dharam R. Kumar, Andrew M. Spring, Chin-Yang Yu, Michael L. Turner

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要旨

The ring opening metathesis polymerisation (ROMP) of three n-octyl substituted [2.2]paracyclophane-1,9-dienes, initiated by Grubbs ruthenium carbene complexes is reported. The molecular weight of the resulting alkyl-substituted poly(p-phenylene vinylene)s is determined by the monomer to initiator ratio and the polymers are isolated with relatively narrow polydispersities and control of the end groups. Only the pseudo-geminal isomer of the tetra-alkyl substituted [2.2]paracyclophane-1,9-diene was susceptible to ROMP. The optical properties of the two series of polymers was investigated.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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Alkyl substituted poly(p-phenylene vinylene)s by ring opening metathesis polymerisation

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