All-thiophene-based conjugated porous organic polymers

文献情報

出版日 2016-07-15

DOI 10.1039/C6PY00725B

インパクトファクター 5.582

著者

Peng-Fei Wang, Hua Wang, Bao-Hang Han

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要旨

Novel all-thiophene-based conjugated porous organic polymers (ThPOP-1 and ThPOP-2) were synthesized through ferric chloride-catalyzed oxidative coupling polymerization at room temperature. ThPOP-1 and ThPOP-2 were characterized via solid-state 13C CP/MAS NMR spectroscopy, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and elemental analysis. The sulfur content of the obtained polymers is approximately 36 wt%. The Brunauer–Emmett–Teller specific surface area results of ThPOP-1 and ThPOP-2 are 1050 and 160 m2 g−1, respectively. Carbon dioxide adsorption isotherms show that ThPOP-1 (15.0 wt%) exhibits a larger uptake capacity than ThPOP-2 (4.0 wt%) at 273 K and 1.0 bar. Hydrogen uptake is also excellent for ThPOP-1 (2.23 wt%) at 77 K and 1.0 bar.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

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All-thiophene-based conjugated porous organic polymers

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