Nonmetal-catalyzed hydroamination of ynamides with amines

文献情報

出版日 2021-09-09

DOI 10.1039/D1QO01052B

インパクトファクター 5.281

著者

Yanru Wang, Zhen Zhao, Songkui Lv, Lixia Ding, Xiao-Na Wang, Junbiao Chang

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要旨

The first metal-free catalytic regioselective hydroamination of ynamides with primary and secondary amines has been achieved by using TfOH as the catalyst under mild reaction conditions. This appealing strategy provides the corresponding N-arylimines and ethene-1,1-diamines in good to excellent yields with wide functional group tolerance. Furthermore, their applications in 2-aminoindole syntheses have been presented.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Nonmetal-catalyzed hydroamination of ynamides with amines

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