Light-induced dipole moment modulation in diarylethenes: a fundamental study
文献情報
Andrea Bianco, Giorgio Ferrari, Rossella Castagna, Andrea Rossi, Marco Carminati, Giorgio Pariani, Matteo Tommasini
The dipole moment of photochromic diarylethenes is determined in solution for both the coloured and uncoloured forms by measuring the capacitance of a capacitor filled with a photochromic solution as a dielectric material. Diarylethenes with different substituents are investigated and the modulation of the dipole moment is related to their chemical structures. We determine a modulation of the dipole moment up to 4 Debye. We discuss the model used to obtain the dipole moment from the capacitance measurements and we compare the experimental results with the outcomes from DFT calculations. The results highlight the importance of conformational effects in the description of the dipole moment of diarylethenes.
おすすめジャーナル

Russian Chemical Reviews

Molecular Pharmacology

Journal of Heterocyclic Chemistry

Fibre Chemistry

Proceedings of the National Academy of Sciences of the United States of America

Helvetica Chimica Acta

Pharmacological Reviews

Pure and Applied Chemistry

Israel Journal of Chemistry

Organic Preparations and Procedures International
関連文献
Improved performance of graphene doped with pyridinic N for Li-ion battery: a density functional theory model
Xiang-kai Kong
DOI: 10.1039/C3CP51987B
Investigation of porosity and heterojunction effects of a mesoporous hematiteelectrode on photoelectrochemical water splitting
Jingling Liu, Muhammad Shahid, Young-Seon Ko, Eunchul Kim, Tae Kyu Ahn, Jong Hyeok Park
DOI: 10.1039/C3CP51053K
A statistical description of the evolution of cloud condensation nuclei activity during the heterogeneous oxidation of squalane and bis(2-ethylhexyl) sebacate aerosol by hydroxyl radicals
Christopher W. Harmon, Christopher R. Ruehl, Christopher D. Cappa, Kevin R. Wilson
DOI: 10.1039/C3CP50347J
Binderless thin films of zeolite-templated carbon electrodes useful for electrochemical microcapacitors with ultrahigh rate performance
Ángel Berenguer-Murcia, Ramiro R. Ruiz-Rosas, Jaime García-Aguilar, Khanin Nueangnoraj, Hirotomo Nishihara, Emilia Morallón, Takashi Kyotani, Diego Cazorla-Amorós
DOI: 10.1039/C3CP51945G
Ambient reaction kinetics of atmospheric oxygenated organics with the OH radical: a computational methodology study
Jonas Elm, Solvejg Jørgensen, Merete Bilde, Kurt V. Mikkelsen
DOI: 10.1039/C3CP50192B
Preparation and characterization of titania-entrapped silica hollow particles: effective dye removal and evidence of selectivity
Kritapas Laohhasurayotin, Duangkamon Viboonratanasri
DOI: 10.1039/C3CP50872B
Charge trapping in TiO2 polymorphs as seen by Electron Paramagnetic Resonance spectroscopy
Mario Chiesa, Maria Cristina Paganini, Stefano Livraghi, Elio Giamello
DOI: 10.1039/C3CP50658D
Stereochemical effects on the aggregation and biological properties of the fibril-forming peptide [KIGAKI]3 in membranes
Parvesh Wadhwani, Johannes Reichert, Erik Strandberg, Jochen Bürck, Julia Misiewicz, Sergii Afonin, Nico Heidenreich, Susanne Fanghänel, Igor V. Komarov
DOI: 10.1039/C3CP50896J
Hydrogenolysis of ethylene glycol to methanol over modified RANEY® catalysts
Cheng-Tar Wu, Jin Qu, Joseph Elliott, Kai Man Kerry Yu, Shik Chi Edman Tsang
DOI: 10.1039/C3CP51619A
こちらもおすすめ
(S)-四氢呋喃-3-羧酸の物理化学的性質は何ですか?
CAS番号168395-26-4の(S)-四氢呋喃-3-羧酸は、白色の結晶が特徴的な性質を持ちます。分子量は128.08であり、水に溶けやすく、アルコールなど...
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物はどのように処理すべきですか?
塩基性硫黄化合物1,3-ジメチル-1-[5-(三氟甲基)-1,3,4-硫杂环己二酮-2-基]尿素を含む廃棄物は、専門的な廃棄処理施設で焼却処理を行うべきです。ま...
インドリジン-2-カルボン酸は安全ですか?
インドリジン-2-カルボン酸は一般的に安全ですが、過度に濃い状態では刺激性があります。取り扱いには適切な防護具を使用し、直接触れや吸入を避ける必要があります。
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールの市場動向や研究トレンドはどうですか?
5-甲基-2-(3-ピリジニル)-1,3-テイゾール-4-オールは、医薬品や農薬、および合成化学の分野において研究が進められています。市場動向としては、化学物質...
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛はどのように保存すればよいですか?
4,4',4''-(嘧啶-2,4,6-三基)三苯甲醛は、密閉容器に保管し、避けておくことが重要です。室温で保管し、直射日光を避けてください。
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールについて、適用される法規ガイドラインは何ですか?
(3aR)-1,3,3-トリフェニルテトラヒドロ-3H-ピロロ[1,2-c][1,3,2]-オキザボロロールは、GHS(国際危険物識別ルール)の分類が適用されま...
6-(4-氯苯氧基)吡啶-3-胺の代替品はありますか?
6-(4-氯苯氧基)吡啶-3-胺の代替品としては、他の芳香族アミン化合物や類似の除草剤が考えられます。ただし、他の化合物と同様に、代替品の選択には安全性と効果性...
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際の実験室安全事項は何ですか?
3-フェニル-3,4-ジヒドロ-2H-1,4-ベンゾキサジンを取り扱う際は、防塵マスク、ゴーグル、ゴム手袋を使用し、ドラフトチャンバー内で作業することを推奨しま...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.



![4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine structure 4-{1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]cyclopropyl}morpholine structure](https://static.chemtradehub.com/structs/120/1206594-08-2-7afb.webp)
