Hydrated forms of fluoroacetic acid: a rotational study

文献情報

出版日 2016-07-30

DOI 10.1039/C6CP04735A

インパクトファクター 3.676

著者

Luca Evangelisti, Lorenzo Spada, Susana Blanco, Walther Caminati

原文を見る

要旨

The rotational spectra of two conformers of the 1 : 1 adduct of fluoroacetic acid with water have been assigned by pulsed jet Fourier transform microwave spectroscopy. Their shapes differ according to the trans and cis forms of the fluoroacetic acid moiety. This is in contrast to the rotational spectrum of the monomer, for which the cis form has not been observed. Details of the hydrogen bond, structure, dynamics and energetic features of the two species are given.

掲載誌

Physical Chemistry Chemical Physics

CiteScore: 5.5

自己引用率: 10.3%

年間論文数: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.