Micelle formation of a non-ionic surfactant in non-aqueous molecular solvents and protic ionic liquids (PILs)
文献情報
Frances Separovic, Calum J. Drummond, Tamar L. Greaves
Many ionic liquids and low molecular weight polar solvents have been reported to support amphiphile self-assembly, with most of these reported for the first time in the last decade. This phenomenon is attributed to the solvophobic effect (analogous to the hydrophobic effect in water). However, to date there has been no systematic study which evaluates micelle formation in a large library of non-aqueous solvents. Here we investigate micelle formation of a non-ionic amphiphile, hexa-ethyleneglycol mono n-dodecyl ether, C12E6, in a diverse range of molecular solvents and protic ionic liquids (PILs). Nine of the 19 non-aqueous molecular solvents investigated, and all four of the PILs, were found to support micelle formation. A link was investigated between the solvent cohesive energy density (as estimated using the Gordon parameter) and both the critical micelle concentration and the related free energy of micellization . In addition, the chemical structure and liquid mesostructure of the solvent were found to be important factors in the ability of the solvents to support micelle formation.
おすすめジャーナル

Journal of Catalysis

Journal of Heterocyclic Chemistry

Helvetica Chimica Acta

Fibre Chemistry

Organic Preparations and Procedures International

Kinetics and Catalysis

Journal of Physics and Chemistry of Solids

European Journal of Wood and Wood Products

Proceedings of the National Academy of Sciences of the United States of America

Pharmacological Reviews
関連文献
Fortification of vegetable fat with natural antioxidants recovered by bergamot pomace for use as an ingredient for the production of biscuits
Amalia Piscopo, Simone Santacaterina, Elisa Imeneo, Alessandra De Bruno, Marco Poiana
DOI: 10.1039/D3FB00125C
New sources of genipin-rich substances for crosslinking future manufactured bio-based materials
Maryam Nejati, Yuan Fang, Boyang Guo, Amparo Jiménez-Quero, Antonio J. Capezza, Marcos A. Sabino
DOI: 10.1039/D3SU00303E
Interactions between liquid ammonia and graphitic materials
Cheng-Wei Lin, Zhiyin Yang, Ailun Huang, Xueying Chang, Chenxiang Wang, Fan Yang, Chen Wei, Markus Thiel, Yuto Katsuyama, Lihua Jin
DOI: 10.1039/D3LF00194F
Encapsulation of fish oil and essential fatty acids by spray drying
Afroza Sultana, Shuji Adachi, Hidefumi Yoshii
DOI: 10.1039/D3FB00099K
Optimization of Pavlova gyrans biomass production and the fatty acid profile using a two-step approach
Filipe Maciel, Hugo Pereira, Joana Silva
DOI: 10.1039/D3FB00110E
Biological and postharvest interventions to manage the ethylene in fruit: a review
Ram Asrey, Swati Sharma, Kalyan Barman, Uma Prajapati, Narender Negi
DOI: 10.1039/D3FB00037K
Recent advancements towards the green synthesis of carbon quantum dots as an innovative and eco-friendly solution for metal ion sensing and monitoring
Jyoti Dhariwal, Gyandshwar K. Rao, Dipti Vaya
DOI: 10.1039/D3SU00375B
Elucidating multiple reaction pathways for the degradation of antibiotics in water by a self-active single-atom zinc catalyst on biochar
Jieming Yuan, Yunkyoung Han, Krishnamoorthy Sathiyan, Virender K. Sharma, Abdol Hadi Mokarizadeh, Mesfin Tsige, Jiechao Jiang, Xingmao Ma
DOI: 10.1039/D3SU00265A
こちらもおすすめ
4'-ブロモビフェニル-3-メトークシーディ.ActionBarはどのように保存すればよいですか?
4'-ブロモビフェニル-3-メトークシーディ.ActionBarは、冷暗所で、直射日光を避け、密栓の容器に保存し、遠隔場所に保管してください。温度は常温(0〜2...
2-異丙基フェニルヒドラジン塩酸塩とは何ですか?
2-異丙基フェニルヒドラジン塩酸塩は、CAS番号58928-82-8を有する化合物で、構造式はC11H14N2HClです。これは塩基性化合物であり、水に溶けやす...
5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンを取り扱う際の実験室安全事項は何ですか?
5-(4-クロロフェニル)-4H-1,2,4-三氮唑-3-アミンは取り扱いに注意が必要です。PPEとして防塵マスク、ゴーグル、手袋を使用し、ドラフトチャンバーを...
去甲基雷贝拉唑硫醚はどのように合成されますか?
去甲基雷贝拉唑硫醚は、ベンジミダゾール硫化物と3-メチル-4-ピリジノールの反応によって合成されます。具体的には、2-チオキシドベンジミダゾールと3-メチル-4...
2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは安全ですか?
2-ブロモ-5-フロロ-N-(2-フェノールメチル)ベンゼンウレアは、毒性や刺激性の実験データに基づき、適切な取扱いと防護措置を講じることで安全に使用できます。...
対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚の物理化学的性質は何ですか?
対甲苯磺酸酯-四聚乙二醇-四氢吡喃醚のCAS番号は86259-89-4です。この化合物は無色の液体で、分子量は約724.8です。高濃度では溶血性が報告されており...
2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環はどのように保存すればよいですか?
2-(3-(二氟甲基)-4-氟苯基)-4,4,5,5-四甲基-1,3,2-二噁硼戊環は、室温で暗い場所に保管し、直射日光から遠ざけ、容器は密閉状態で保存してくだ...
6-アミノ-5-クロロ-2-シクロプロピルピリミジンカルボン酸の代替品はありますか?
この化合物の代替品には、ピロリミジン酸やその類似物、またピロリミジンカルボン酸の他の異性体があります。これらの代替品は、特定の化学反応や目的に応じて選択すること...
5-クロロベンゾ[1,3]二オキセイン-4-アミンに適用される法規ガイドラインは何ですか?
5-クロロベンゾ[1,3]二オキセイン-4-アミンはCAS番号379228-45-2に該当します。この化合物はGHS分類でH314(接触により急性毒性がある)と...
掲載誌
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.


![{3-[Bis(4-hydroxyphenyl)methyl]-1-[2-(dimethylamino)ethyl]-1H-indol-2-yl}[4-(2-chlorophenyl)-1-piperazinyl]methanone structure {3-[Bis(4-hydroxyphenyl)methyl]-1-[2-(dimethylamino)ethyl]-1H-indol-2-yl}[4-(2-chlorophenyl)-1-piperazinyl]methanone structure](https://static.chemtradehub.com/structs/170/170365-25-0-e4d7.webp)

