Alkylation/1,2-aryl migration of α-aryl allylic alcohols with α-carbonyl alkyl bromides using visible-light photoredox catalysis

文献情報

出版日 2015-09-01

DOI 10.1039/C5QO00220F

インパクトファクター 5.281

著者

Yang Li, Bang Liu, Xuan-Hui Ouyang, Ren-Jie Song

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要旨

A novel visible-light-induced alkene difunctionalization strategy is described for the synthesis of 1,5-dicarbonyl compounds from two reaction partners, α-aryl allylic alcohols and α-carbonyl alkyl bromides. This method is successful by sequential alkylation of an alkene C–C double bond and intramolecular 1,2-aryl migration, and shows a broad substrate scope, excellent functional group tolerance and good selectivity.

掲載誌

Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Alkylation/1,2-aryl migration of α-aryl allylic alcohols with α-carbonyl alkyl bromides using visible-light photoredox catalysis

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