Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions

文献情報

出版日 2015-02-11

DOI 10.1039/C5QO00023H

インパクトファクター 5.281

著者

Dapeng Zhu, Xin Cao, Biao Yu

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要旨

A linear η2-alkyne π complex of [Ph3PAu]+, namely Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex (1), was prepared and characterized. The new complex is found to be shelf-stable and effective for a range of the Au(I)-catalyzed alkyne π activation reactions, including a glycosylation reaction with glycosyl ortho-alkynylbenzoates as donors.

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Organic Chemistry Frontiers

CiteScore: 7.8

自己引用率: 8.7%

年間論文数: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions

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