Supramolecular polymerization of supramonomers: a way for fabricating supramolecular polymers

文献情報

出版日 2014-07-16

DOI 10.1039/C4PY00942H

インパクトファクター 5.582

著者

Qiao Song, Fei Li, Xinxin Tan, Liulin Yang, Zhiqiang Wang, Xi Zhang

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要旨

This communication describes a new method of fabricating supramolecular polymers through supramolecular polymerization of supramonomers. To mix building blocks of Phe-Gly-Gly linked with an azobenzene group and cucurbit[8]uril (CB[8]) in a molar ratio of 2 : 1 in aqueous solutions, supramonomers were obtained by host–guest interaction between tripeptide and CB[8]. Then supramolecular polymers were formed spontaneously by mixing the supramonomers with bis-β-cyclodextrins in a molar ratio of 1 : 1 in an aqueous solution through noncovalent host–guest complexation of the azobenzene group and β-cyclodextrin. Considering that various noncovalent interactions can be used to drive the formation of supramonomers and the supramolecular polymerization of the supramonomers, this study can enrich the methodology of fabricating supramolecular polymers.

掲載誌

Polymer Chemistry

CiteScore: 8.6

自己引用率: 7.3%

年間論文数: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Supramolecular polymerization of supramonomers: a way for fabricating supramolecular polymers

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